The role of mono-atomic steps and of step decoration by Cu on the adsorption and hydrogenatio of benzene and cyclohexene on Pt single crystal electrodes

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Authors

LOEFFLER Thomas BUSSAR R. DRBÁLKOVÁ Eva JANDERKA Pavel BALTRUSCHAT Helmut

Year of publication 2003
Type Article in Periodical
Magazine / Source Electrochimica Acta
MU Faculty or unit

Faculty of Science

Citation
Field Electrochemistry
Keywords Adsorption; hydrogenation; benzene; Electrocatalysis; DEMS
Description The adsorption of benzene and cyclohexene was studied at stepped Pt(332) and at the Pt(111) electrode surface usinf differential electrochemical spectrometry (DEMS). The experiments involve desorption and hydrogenation in the hydrogen region, oxidation in the oxygen adsorption region and non-reactive displacement by underpotential deposition of Cu.
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